Thermoelectricity of EuCu<sub>2</sub>(Ge<sub>1-x</sub>Si<sub>x</sub>)<sub>2</sub> intermetallics

TitleThermoelectricity of EuCu2(Ge1-xSix)2 intermetallics
Publication TypeJournal Article
Year of Publication2006
AuthorsZlatic, V., Monnier R., and Freericks J. K.
Refereed DesignationRefereed
JournalPhysica B: Condensed Matter
Volume378-380
Pagination661 - 662
Abstract

The evolution of the thermopower S(T) of EuCu2(Ge1-xSix)2 intermetallics, which is induced by the Si–Ge substitution, is explained by the Kondo scattering of conduction electrons on the Eu ions which fluctuate between the magnetic 2+ and non-magnetic 3+ Hund’s rule configurations. The Si–Ge substitution is equivalent to chemical pressure which modifies the coupling and the relative occupation of the f and conduction states.

DOI10.1016/j.physb.2006.01.448
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